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    兰州市城区夏季大气挥发性有机物污染特征及来源解析

    Pollution Characteristics and Sources Apportionment of Atmospheric Volatile Organic Compounds in Summer in Lanzhou Urban Area

    • 摘要: 2020年7月对兰州市城区大气挥发性有机物进行连续24 h测定,研究其污染特征和臭氧生成潜势等,并进行来源解析。结果表明:兰州超级站点 VOCs的平均质量浓度为99.59 μg/m3,各类挥发性有机物中烷烃占比最大,占总挥发性有机物浓度的33.81%;对挥发性有机物进行臭氧生成潜势分析,排名靠前的物种为甲苯、乙烯、乙酸乙烯酯;利用PMF模型对挥发性有机物进行源解析,结果显示VOCs来源贡献为机动车源(31.30%)、油气挥发或泄漏(24.10%)、溶剂使用源(18.60%)、燃烧和化工工艺源(17.20%)、天然源(8.80%)。建议将控制机动车排放、油气挥发和泄漏、溶剂使用等作为消减城市大气挥发性有机物和臭氧污染的重点。

       

      Abstract: In July,a typical summer month in Lanzhou,the atmospheric volatile organic compounds were determined for 24 consecutive hours to study the pollution characteristics,ozone generation potential and source apportionment.The results showed that the average concentration of VOCs in Lanzhou super station was 99.59 μ g/m3.Alkanes accounted for 33.81% of the total VOCs concentration,which was the largest proportion of various organic substances.The ozone generation potential of VOCs was analyzed,and the top species were toluene,ethylene and vinyl acetate.According to sources apportionment for the VOCs by PMF model,the results showed that the sources of VOCs were mainly motor vehicles (31.30%),oil and gas volatilization/leakage (24.10%),solvent use (18.60%),combustion and chemical processes (17.20%),natural sources (8.80%).It was suggested that the control of motor vehicle emissions,oil and gas volatilization/leakage and solvent use should be the focus of reducing urban atmospheric VOCs emissions and ozone pollution prevention and control.

       

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