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    超低温冷阱结构优化及其对温室气体浓度测量的影响

    Optimisation of Ultra-low Temperature Cold Trap Structure and Its Effect on Greenhouse Gas Concentration Measurements

    • 摘要: 随着全球气候变化的加剧,温室气体的监测与分析变得愈发重要。全自动超低温冷阱作为温室气体观测系统中的关键组件,在温室气体观测中发挥着至关重要的作用。通过去除样气中的水汽,分析主机的灵敏度和准确性得到提高,使用寿命延长。针对采样泵至分析主机的保留时间超过1 min,冷阱管切换对CO2、CH4浓度测量的影响时长超过3 min和进入分析主机的H2O(g)含量大于40×10-6等问题,该研究通过优化冷阱管的结构,探讨了其对系统保留时间和系统性能的影响,以及冷阱管切换对温室气体浓度测量的影响时间。首先,通过减小冷阱管容积,缩短了样气在冷阱内的滞留时间,提高了测量实时性;其次,将传统依赖电磁阀的排水方式升级为蠕动泵连续排水方式,使冷阱出水口保持常通、稳流的排水状态,有效避免了排水间歇期因负压或压力波动导致的室内空气倒吸回流,消除了室内空气对样气测量的干扰。结果表明:优化后,样气通过预处理系统的保留时间显著缩短,平均时间为57.58 s,小于1 min,满足规定要求;3次冷阱管切换时,H2O(g)浓度最高值分别为12.93×10-6、14.36×10-6、12.94×10-6,均满足小于40×10-6的技术要求,冷阱管切换对温室气体浓度测量造成影响的时长分别为1.75、1.53、2.01 min,均满足小于3 min的技术要求,整体上满足了分析主机对样气测量的要求。经过结构优化的超低温冷阱不仅满足了分析主机对样气测量的要求,还为温室气体监测系统的设计提供了新的思路,进一步提升了超低温冷阱的性能,为应对气候变化与"双碳"目标提供了更为精准的数据支撑。

       

      Abstract: With the intensification of global climate change,the monitoring and analysis of greenhouse gases (GHGs) have become increasingly critical.As a pivotal component in greenhouse gas observation systems,the fully automatic ultra-low temperature cold trap plays an essential role by eliminating water vapor from sampled gases,thereby enhancing the sensitivity and accuracy of the analytical instruments and extending their operational lifespan.To address issues such as the retention time from the sampling pump to the analytical instrument,the duration of the impact of gaseous water on CO2 and CH4 concentration measurements,and excessive H2O(g) ingress during cold trap tube switching (exceeding technical thresholds),this study reduces the structure of the cold trap and analyzes its effects on system retention time,performance,and the impact duration on greenhouse gas concentration measurements during cold trap switching.By reducing the internal volume of the cold trap tube,the residence time of the sample gas in the cold trap is shortened.Additionally,the conventional solenoid valve drainage method is replaced with peristaltic pump drainage method to ensure that the water outlet maintains in a constant drainage state,preventing the return of indoor air to the cold trap tube,improving drainage efficiency and eliminating the interference from indoor air on the measurement of sample gas.The results show that after optimization,the retention time of the sample gas through the pretreatment system is significantly shortened,with an average time is 57.58 s,which is less than 1 min,meeting the specified requirements.the peak H2O(g) concentrations during the three cold trap tube switching events are 12.93×10-6,14.36×10-6,and 12.94×10-6,all meeting the technical requirements of being less than 40×10-6.The impact durations on the measurement of greenhouse gas concentration are 1.75 min,1.53 min and 2.01 min,respectively,all meeting the technical requirement of being less than 3min,ensuring that the sample gas meets the requirements of the analytical instrument.The structurally optimized ultra-low temperature cold trap not only fulfills the stringent requirements of the analyzing host for the measurement of sample gas,but also provides new ideas for the design of the greenhouse gas monitoring systems,further improving the performance of the ultra-low temperature cold trap,and providing more accurate data support for addressing climate change and achieving the goals of "dual carbon".

       

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