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    基于走航监测的北京市工业园区VOCs浓度特征分析

    Characteristics of VOCs Concentration in Beijing Industrial Parks Based on Vehicle-mounted Mobile Monitoring

    • 摘要: 为明确北京市各工业园区VOCs浓度及特征,2021年7月—2024年6月对北京市主要工业园区开展了多轮VOCs走航监测。结果表明:研究期间,所有工业园区ρ(TVOC)的平均值为66.3 μg/m3,浓度范围为57.7~149.1 μg/m3,与当天环境空气VOCs浓度的比值范围为1.7~3.9,其中石化园区的整体排放较高。石化园区的高值点位数量最多,占全部工业园区的27.4%,而汽修集群的高值点位平均浓度最高。汽修集群的高值点位主要出现在白天,而其余工业园区的高值点位则主要出现在夜间。从季度变化上看,工业园区整体都存在第二季度和第三季度排放较高,第一季度和第四季度排放较低的变化规律,主要受到企业减排、假期停工和环境温度差异等因素影响。从年度变化上看,多数工业园区在这3年中的排放呈现先上升后下降的变化趋势,这与复工复产排放加强及VOCs专项治理有效管控等因素相关。利用WRF-Flexpart模型对工业园区典型高值点位开展精准溯源,识别污染企业位置,发现相关企业存在厂房密封不严及净化设施状态异常等问题。研究显示,应进一步加强石化园区的VOCs管控,降低汽修集群的高值点位浓度,并强化夏季工业园区的VOCs综合治理,利用高值点位溯源等手段发现并解决工业园区的异常排放,从而降低北京市工业园区VOCs浓度水平。

       

      Abstract: To clarify the concentration and characteristics of VOCs in various industrial parks in Beijing,multiple rounds of VOCs vehicle-mounted mobile monitoring were carried out in major industrial parks in Beijing from July 2021 to June 2024.The results showed that:During the research period,the average value of ρ(TVOC) in all industrial parks was 66.3 μg/m3,with concentrations ranging from 57.7 μg/m3 to 149.1 μg/m3.The ratio to ambient VOCs concentrations on the same day ranged from 1.7 and 3.9,with petrochemical park exhibiting relatively higher overall emissions.Petrochemical park had the largest number of high-value points,accounting for 27.4% of all industrial parks,while auto repair clusters had the highest average concentration at high-value points.Except for auto repair clusters,high-value points in other industrial parks mainly appeared at night,whereas those in auto repair clusters mainly appeared during the day.In terms of seasonal variation,industrial parks generally exhibited a pattern of stronger emissions in the second and third quarters,and weaker emissions in the first and fourth quarters,mainly affected by factors such as corporate emission reductions,holiday shutdowns,and differences in ambient temperature.In terms of annual variation,emissions from most industrial parks showed a trend of first increasing and then decreasing over the past three years,which was related to factors such as the intensification of emissions after resumption of work and production,as well as the effective control of VOCs special treatment.Through the WRF-Flexpart model,precise source tracing was carried out at typical high-value points in industrial parks,identifying the locations of polluting enterprises.It was found that the relevant enterprises had problems such as inadequate sealing of factory buildings and abnormal status of purification facilities.The research indicates that further efforts should be made to strengthen VOCs control in petrochemical parks,reduce the concentration at high-value points in auto repair clusters,and enhance comprehensive VOCs management in industrial parks during summer.Abnormal emissions in industrial parks should be discovered and resolved by tracing the source of high-value points,thereby reducing the VOCs concentration level in Beijing's industrial parks.

       

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