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    典型村落雨水径流溶解性有机质污染特征及源解析

    Pollution Characteristics and Source Apportionment of Dissolved Organic Matter in Stormwater Runoff of Typical Villages

    • 摘要: 村落是以农村居民生活为主体功能的国土空间。农村特殊的生产生活方式和相对落后的基础建设,决定了村落污染具有来源广泛、排放分散、成分复杂等特点。相对于农业生产,村落污染具有明显的空间异质性,且容易被忽视。调查平原地区村落污染特征和贡献等问题,可为改善农村生态环境提供科学依据,对于实现乡村振兴、低碳发展具有重要意义。该研究选择沧州市盐山县典型村落为研究对象,通过污染源调查、降雨过程监测等明确降雨冲刷作用下村落空间污染物全过程动态变化规律和输出效应;通过紫外-可见吸收光谱分析法、傅里叶红外以及三维荧光光谱法对村落不同采样点雨水径流的污染物进行DOM特征解析以及溯源。结果显示:村落排水口BOD5、COD、TN、TP、NH3-N、DO、粪大肠菌群、高锰酸盐指数均超出地表水Ⅲ类水标准,表明村落污染输出成分复杂;空间上,降雨径流水质污染由低向高依次为屋顶、院落、硬化地面、村口;时间上,降雨初期形成的径流污染最重,污染物浓度随降雨持续时间呈降低的趋势;村落DOM具有强烈的微生物来源特征,村口排水的腐殖化程度最高,硬化地面的芳香性最高,农村生产生活过程中产生的生活污水、垃圾粪便、秸秆树叶、农药化肥和农机油污抛洒泄漏等是污染的主要来源。

       

      Abstract: Village are territorial spaces primarily functioning as residential areas for rural residents.The special production and lifestyle of rural areas,coupled with underdeveloped infrastructure construction,determine that village pollution has the characteristics of diverse sources,scattered emissions,and complex components.Compared with agricultural areas,village pollution exhibits obvious spatial heterogeneity and is often overlooked.Clarifying the characteristics and contribution of village pollution in plain areas can provide scientific basis for improving the rural ecological environment,and is of great significance for realizing rural revitalization and low-carbon development.In this study,a typical village in Yanshan County of Cangzhou City was selected as the research object.Through pollution source investigation and rainfall process monitoring,the whole process dynamic variation patterns and output effects of spatial pollutants in villages under rainfall erosion were clarified.The dissolved organic matter (DOM) characteristics and sources of stormwater runoff pollutants at different sampling sites in the village were analyzed and traced by UV-VIS absorption spectroscopy,Fourier infrared spectroscopy,and three-dimensional fluorescence spectroscopy.The results showed that the levels of BOD5,COD,TN,TP,NH3-N,DO,fecal coliform,and permanganate index at the village drainage outlet all exceeded the class Ⅲ standard of national surface water,indicating that the export components of village pollution were complex.Spatially,the water quality of stormwater runoff pollution ranked from low to high as follows: roof,courtyard,hardened ground,and village entrance.Temporally,the rainfall pollution in the early period of village pollution output was the heaviest,and pollutant concentrations tended to decrease with rainfall duration.Village DOM exhibited strong characteristics of microbial sources,with the highest degree of humification in the drainage at the village entrance and the highest aromatization of the hardened ground.The main sources of pollution were domestic sewage,garbage and feces,straw and leaves,as well as the spilling and leaking of pesticides and fertilizers and agricultural machinery oil.

       

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