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    基于同位素示踪的地下水环境质量监测点硫酸盐来源解析

    Source Apportionment of Sulfate at Groundwater Environmental Quality Monitoring Sites Based on Isotope Tracing

    • 摘要: 全球约有156个国家监测到地下水中硫酸盐超标,地下水硫酸盐污染会对人类健康和生态系统平衡造成威胁。开展地下水硫酸盐超标溯源监测并识别其来源,是地下水污染源头管控的重要基础。综合运用现场调查、井下电视探测以及水化学、同位素示踪等多种方法开展了地下水环境质量监测点硫酸盐来源解析研究。结果表明:目标监测点所在的小区域水环境中,枯水期和丰水期硫酸盐含量均较高,Sr同位素比值较小,集中分布区间为0.711~0.712,硫酸盐同位素组成表现出相对富集重同位素的特征,δ34S-SO42-值高于15‰,δ18O-SO42-值高于10‰;水化学和同位素等多方面证据指示,目标监测点地下水中硫酸盐主要来源为蒸发盐岩溶解,硫化物氧化也有一定贡献,与主成分分析的物质来源分类结果一致。该研究可为环境质量监测点小区域地下水超标成因解析提供方法指导,为地下水环境管理提供重要科学参考。

       

      Abstract: Approximately 156 countries worldwide have detected sulfate concentrations exceeding permissible levels in groundwater.Sulfate contamination in groundwater poses a threat to human health and the balance of ecosystems.Conducting monitoring and source apportionment of sulfate in groundwater is crucial for the control of groundwater pollution sources.A study on the source apportionment of sulfate at groundwater environmental quality monitoring sites was conducted using a combination of methods including field investigations,borehole television detection,and hydrochemical and isotopic tracing.The results indicate that in the localized water environment of the target monitoring site,sulfate concentrations are relatively high during both dry and wet seasons,with Sr isotope ratios being relatively low and concentrated in the range of 0.711-0.712.The sulfate isotope composition is relatively enriched,with δ34S-SO42- distribution ratios exceeding 15‰ and δ18O-SO42- distribution ratios exceeding 10‰.Multiple lines of evidence from hydrochemistry and isotopes suggest that the primary source of sulfate in the groundwater at the target groundwater monitoring well is the dissolution of evaporative rock salt,with a certain contribution from sulfide oxidation,which is consistent with the source classification results of material sources obtained from principal component analysis.This study provides methodological guidance for analyzing the causes of groundwater exceedances in small-scale areas around environmental quality monitoring wells and offers important scientific support for groundwater environmental management.

       

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